Dispersion‐Driven Hydrogen Bonding: Predicted Hydrogen Bond between Water and Platinum(II) Identified by Neutron Diffraction | Zendy

Rizzato Silvia | Zendy; Bergès Jacqueline | Zendy; Mason Sax A. | Zendy; Albinati Alberto | Zendy; Kozelka Jiří | Zendy

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Dispersion‐Driven Hydrogen Bonding: Predicted Hydrogen Bond between Water and Platinum(II) Identified by Neutron Diffraction

Author(s) -

Rizzato Silvia,

Bergès Jacqueline,

Mason Sax A.,

Albinati Alberto,

Kozelka Jiří

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001892

Subject(s) - neutron diffraction , hydrogen bond , lewis acids and bases , chemistry , crystallography , platinum , molecule , london dispersion force , ab initio quantum chemistry methods , hydrogen , ab initio , dispersion (optics) , metal , inorganic chemistry , computational chemistry , crystal structure , organic chemistry , catalysis , physics , van der waals force , optics

An alternative to classical? In square‐planar d 8 complexes the metal ion can interact with axial H 2 O molecules either as a Lewis acid or as a Lewis base. Ab initio calculations predicted that uncharged Pt II complexes form a hydrogen‐bond‐like interaction with H 2 O, in which Pt II acts as a Lewis base. Such a nonclassical OH⋅⋅⋅Pt hydrogen bond has now been identified in crystals of trans ‐[PtCl 2 (NH 3 )( N ‐glycine)]⋅H 2 O by neutron diffraction.

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