Premium
Rhodium‐Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands
Author(s) -
Wang ZhiQian,
Feng ChenGuo,
Zhang ShuSheng,
Xu MingHua,
Lin GuoQiang
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001883
Subject(s) - conjugate , diene , nitroalkene , rhodium , catalysis , chemistry , bicyclic molecule , medicinal chemistry , combinatorial chemistry , organic chemistry , enantioselective synthesis , mathematics , mathematical analysis , natural rubber
Old before I diene : An efficient rhodium/diene‐catalyzed asymmetric conjugate addition of organoboronic acids to challenging nitroalkene substrates that lack α substituents has been developed. Chiral bicyclo[3.3.0] dienes were found to be superior ligands under ArB(OH) 2 /KHF 2 conditions. Np=naphthyl.