Rhodium‐Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands | Zendy

Wang ZhiQian | Zendy; Feng ChenGuo | Zendy; Zhang ShuSheng | Zendy; Xu MingHua | Zendy; Lin GuoQiang | Zendy

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Rhodium‐Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands

Author(s) -

Wang ZhiQian,

Feng ChenGuo,

Zhang ShuSheng,

Xu MingHua,

Lin GuoQiang

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001883

Subject(s) - conjugate , diene , nitroalkene , rhodium , catalysis , chemistry , bicyclic molecule , medicinal chemistry , combinatorial chemistry , organic chemistry , enantioselective synthesis , mathematics , mathematical analysis , natural rubber

Old before I diene : An efficient rhodium/diene‐catalyzed asymmetric conjugate addition of organoboronic acids to challenging nitroalkene substrates that lack α substituents has been developed. Chiral bicyclo[3.3.0] dienes were found to be superior ligands under ArB(OH) 2 /KHF 2 conditions. Np=naphthyl.

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