Anomalous Surface Compositions of Stoichiometric Mixed Oxide Compounds | Zendy

Merzlikin Sergiy V. | Zendy; Tolkachev Nikolay N. | Zendy; Briand Laura E. | Zendy; Strunskus Thomas | Zendy; Wöll Christof | Zendy; Wachs Israel E. | Zendy; Grünert Wolfgang | Zendy

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Anomalous Surface Compositions of Stoichiometric Mixed Oxide Compounds

Author(s) -

Merzlikin Sergiy V.,

Tolkachev Nikolay N.,

Briand Laura E.,

Strunskus Thomas,

Wöll Christof,

Wachs Israel E.,

Grünert Wolfgang

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001804

Subject(s) - stoichiometry , oxide , calcination , surface (topology) , mixed oxide , scattering , chemical engineering , materials science , chemistry , mineralogy , computer science , chemical physics , physics , catalysis , metallurgy , mathematics , optics , organic chemistry , engineering , geometry

Coated : Surface analytical studies (including low‐energy ion scattering (LEIS)) show that the outer surface of bulk, stoichiometric mixed vanadates and molybdates can be strongly enriched with VO x or MoO x species. Such surface reconstruction even in the calcined initial state has implications for the discussion of catalytic and other materials properties.

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