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A Noble‐Metalate Bowl: The Polyoxo‐6‐vanado(V)‐7‐palladate(II) [Pd 7 V 6 O 24 (OH) 2 ] 6−
Author(s) -
Izarova Natalya V.,
Vankova Nina,
Banerjee Abhishek,
Jameson Geoffrey B.,
Heine Thomas,
Schinle Florian,
Hampe Oliver,
Kortz Ulrich
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001738
Subject(s) - square (algebra) , content (measure theory) , tetrahedron , crystallography , mass spectrometry , physics , spectroscopy , combinatorics , chemistry , mathematics , quantum mechanics , geometry , mathematical analysis
Nobly born : The bowl‐shaped noble metalate [Pd II 7 V V 6 O 24 (OH) 2 ] 6− (Pd 7 V 6 ) comprises seven square‐planar Pd II O 4 units as well as four tetrahedral V V O 4 and two square‐pyramidal V V O 5 addenda units (see picture). The solution stability of Pd 7 V 6 has been demonstrated by 51 V NMR spectroscopy, ESI mass spectrometry, and DFT calculations.