A Noble‐Metalate Bowl: The Polyoxo‐6‐vanado(V)‐7‐palladate(II) [Pd 7 V 6 O 24 (OH) 2 ] 6− | Zendy

Izarova Natalya V. | Zendy; Vankova Nina | Zendy; Banerjee Abhishek | Zendy; Jameson Geoffrey B. | Zendy; Heine Thomas | Zendy; Schinle Florian | Zendy; Hampe Oliver | Zendy; Kortz Ulrich | Zendy

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A Noble‐Metalate Bowl: The Polyoxo‐6‐vanado(V)‐7‐palladate(II) [Pd 7 V 6 O 24 (OH) 2 ] 6−

Author(s) -

Izarova Natalya V.,

Vankova Nina,

Banerjee Abhishek,

Jameson Geoffrey B.,

Heine Thomas,

Schinle Florian,

Hampe Oliver,

Kortz Ulrich

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001738

Subject(s) - square (algebra) , content (measure theory) , tetrahedron , crystallography , mass spectrometry , physics , spectroscopy , combinatorics , chemistry , mathematics , quantum mechanics , geometry , mathematical analysis

Nobly born : The bowl‐shaped noble metalate [Pd II 7 V V 6 O 24 (OH) 2 ] 6− (Pd 7 V 6 ) comprises seven square‐planar Pd II O 4 units as well as four tetrahedral V V O 4 and two square‐pyramidal V V O 5 addenda units (see picture). The solution stability of Pd 7 V 6 has been demonstrated by 51 V NMR spectroscopy, ESI mass spectrometry, and DFT calculations.

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