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A Highly Porous Metal–Organic Framework with Open Nickel Sites
Author(s) -
Gedrich Kristina,
Senkovska Irena,
Klein Nicole,
Stoeck Ulrich,
Henschel Antje,
Lohe Martin R.,
Baburin Igor A.,
Mueller Uwe,
Kaskel Stefan
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001735
Subject(s) - polyhedron , nickel , metal organic framework , methane , computer science , chemistry , nanotechnology , earth science , materials science , chemical engineering , geology , engineering , combinatorics , organic chemistry , mathematics , adsorption
A healthy appetite : A new metal–organic framework (DUT‐9; see picture) has an unprecedented topology that contains {Ni 5 (μ 3 ‐O) 2 (CO 2 ) 6 } clusters (green polyhedra; C gray, O red). DUT‐9 has very high storage capacities for methane, hydrogen, and carbon dioxide because of the presence of open metal sites (marked by stars).