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Oriented Nanoscale Films of Metal–Organic Frameworks By Room‐Temperature Gel‐Layer Synthesis
Author(s) -
Schoedel Alexander,
Scherb Camilla,
Bein Thomas
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001684
Subject(s) - ethylene glycol , monolayer , nanoscopic scale , layer (electronics) , metal , nanotechnology , materials science , metal organic framework , linker , layer by layer , chemical engineering , chemistry , computer science , organic chemistry , metallurgy , adsorption , engineering , operating system
MOF Brylcreem : A gel‐layer‐based strategy is used for the growth of highly oriented thin films of metal–organic frameworks on self‐assembled monolayers attached to a gold slide. The monolayer is loaded with the metal‐salt‐containing poly(ethylene glycol) gel layer (see picture; metal ions in red) and covered with a solution containing the linker molecules (blue).