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Porous Metal Carboxylate Boron Imidazolate Frameworks
Author(s) -
Zheng Shoutian,
Wu Tao,
Zhang Jian,
Chow Mina,
Nieto Ruben A.,
Feng Pingyun,
Bu Xianhui
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001675
Subject(s) - sorption , imidazolate , metal organic framework , porosity , carboxylate , boron , carbon fibers , chemical engineering , materials science , porous medium , metal , gas phase , nanotechnology , inorganic chemistry , adsorption , chemistry , organic chemistry , engineering , metallurgy , composite material , composite number
A sponge for carbon : A new family of porous materials with tunable gas sorption properties has been prepared by integrating metal carboxylates and boron imidazolates under hydro‐ or solvothermal conditions. One hydrothermally synthesized phase exhibits very high volumetric CO 2 storage capacity of 81 L L −1 (273 K, 1 atm).