A Docosanuclear {Mo 8 Mn 14 } Cluster Based on [Mo(CN) 7 ] 4− | Zendy

Wang XinYi | Zendy; Prosvirin Andrey V. | Zendy; Dunbar Kim R. | Zendy

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A Docosanuclear {Mo 8 Mn 14 } Cluster Based on [Mo(CN) 7 ] 4−

Author(s) -

Wang XinYi,

Prosvirin Andrey V.,

Dunbar Kim R.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001664

Subject(s) - cyanide , cluster (spacecraft) , crystallography , paramagnetism , nitrile , molecule , computer science , chemistry , information retrieval , combinatorics , materials science , physics , mathematics , condensed matter physics , inorganic chemistry , organic chemistry , computer network

I'll take the high road : An anionic nanosize docosanuclear {Mo 8 Mn 14 } cluster based on the [Mo(CN) 7 ] 4− unit was synthesized and fully characterized by X‐ray and magnetic studies. This molecule (see picture; Mo red, Mn purple, C gray, N blue) is the first discrete compound based on [Mo(CN) 7 ] 4− and contains the most paramagnetic centers (22) and the largest ground state spin value ( S =31) for a cyanide‐bridged cluster.

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