Premium
A Docosanuclear {Mo 8 Mn 14 } Cluster Based on [Mo(CN) 7 ] 4−
Author(s) -
Wang XinYi,
Prosvirin Andrey V.,
Dunbar Kim R.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001664
Subject(s) - cyanide , cluster (spacecraft) , crystallography , paramagnetism , nitrile , molecule , computer science , chemistry , information retrieval , combinatorics , materials science , physics , mathematics , condensed matter physics , inorganic chemistry , organic chemistry , computer network
I'll take the high road : An anionic nanosize docosanuclear {Mo 8 Mn 14 } cluster based on the [Mo(CN) 7 ] 4− unit was synthesized and fully characterized by X‐ray and magnetic studies. This molecule (see picture; Mo red, Mn purple, C gray, N blue) is the first discrete compound based on [Mo(CN) 7 ] 4− and contains the most paramagnetic centers (22) and the largest ground state spin value ( S =31) for a cyanide‐bridged cluster.