Inside Cover: A Simple Route to Univalent Gallium Salts of Weakly Coordinating Anions (Angew. Chem. Int. Ed. 18/2010) | Zendy

Slattery John M. | Zendy; Higelin Alexander | Zendy; Bayer Thomas | Zendy; Krossing Ingo | Zendy

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Inside Cover: A Simple Route to Univalent Gallium Salts of Weakly Coordinating Anions (Angew. Chem. Int. Ed. 18/2010)

Author(s) -

Slattery John M.,

Higelin Alexander,

Bayer Thomas,

Krossing Ingo

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001595

Subject(s) - gallium , homoleptic , phosphine , cover (algebra) , simple (philosophy) , ion , salt (chemistry) , materials science , planar , inorganic chemistry , chemistry , polymer chemistry , organic chemistry , computer science , catalysis , engineering , mechanical engineering , philosophy , computer graphics (images) , epistemology , metal

Gallium(I) salts of weakly coordinating anions (WCAs), which are excellent sources of gallium in the oxidation state +1, are generated by a simple, high‐yielding route. These salts open new areas of low‐valent gallium chemistry that were previously inaccessible. In their Communication on page 3228 ff., I. Krossing, J. M. Slattery, and co‐workers describe a salt of the [Ga(PPh 3 ) 3 ] + ion as an example of a homoleptic gallium–phosphine complex.

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