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Generating Reactive MILs: Isocyanate‐ and Isothiocyanate‐Bearing MILs through Postsynthetic Modification
Author(s) -
Volkringer Christophe,
Cohen Seth M.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001527
Subject(s) - isocyanate , phosgene , bearing (navigation) , isothiocyanate , chemistry , reagent , organic chemistry , computer science , polyurethane , artificial intelligence
MILs hold up : Robust aluminum‐based metal–organic frameworks (MIL‐53(Al)‐NH 2 ) can undergo postsynthetic modification with phosgene reagents to produce highly reactive, porous materials bearing isocyanate or isothiocyanate groups (see scheme).