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Expanding the Scope of Metal‐Free Catalytic Hydrogenation through Frustrated Lewis Pair Design
Author(s) -
Erős Gábor,
Mehdi Hasan,
Pápai Imre,
Rokob Tibor András,
Király Péter,
Tárkányi Gábor,
Soós Tibor
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001518
Subject(s) - frustrated lewis pair , chemoselectivity , scope (computer science) , aside , reactivity (psychology) , frustration , catalysis , lewis acids and bases , computer science , chemistry , world wide web , psychology , organic chemistry , social psychology , medicine , art , literature , pathology , alternative medicine , programming language
No metal causes frustration : Based on a conceptual framework, novel frustrated Lewis acid–base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional‐group tolerance, unique chemoselectivity can be achieved in catalytic metal‐free hydrogenations (see scheme).