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Preparation of Ligand‐Stabilized [P 4 O 4 ] 2+ by Controlled Hydrolysis of a Janus Head Type Diphosphorus Trication
Author(s) -
Weigand Jan J.,
Feldmann KaiOliver,
Echterhoff Antje K. C.,
Ehlers Andreas W.,
Lammertsma Koop
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001363
Subject(s) - cationic polymerization , janus , chemistry , dication , hydrolysis , ligand (biochemistry) , computer science , combinatorial chemistry , information retrieval , organic chemistry , molecule , programming language , biochemistry , receptor
A door to new opportunities : The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand‐stabilized dication that contains a novel cationic [P 4 O 4 ] 2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems.