Cleavage of the SnSn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π‐Bound Inverse Sandwich Complex [(Ar′Sn) 2 (μ 2 ‐η 2 :η 3 ‐cot)] | Zendy

Summerscales Owen T. | Zendy; Wang Xinping | Zendy; Power Philip P. | Zendy

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Cleavage of the SnSn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π‐Bound Inverse Sandwich Complex [(Ar′Sn) 2 (μ 2 ‐η 2 :η 3 ‐cot)]

Author(s) -

Summerscales Owen T.,

Wang Xinping,

Power Philip P.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001276

Subject(s) - cyclooctatetraene , inverse , cleavage (geology) , tin , bond cleavage , ring (chemistry) , chemistry , combinatorics , stereochemistry , mathematics , molecule , materials science , organic chemistry , geometry , catalysis , fracture (geology) , composite material

The adventures of tin‐tin : The activation of cyclooctatetraene by a distannyne results in complete SnSn bond cleavage and formation of a π‐bound planar aromatic C 8 H 8 ring in an inverse sandwich complex (see scheme; Ar′=C 6 H 3 ‐2,6‐(C 6 H 3 ‐2,6‐ i Pr 2 ) 2 )

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