Access to Well‐Defined Ruthenium(I) and Osmium(I) Metalloradicals | Zendy

Takaoka Ayumi | Zendy; Gerber Laura C. H. | Zendy; Peters Jonas C. | Zendy

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Access to Well‐Defined Ruthenium(I) and Osmium(I) Metalloradicals

Author(s) -

Takaoka Ayumi,

Gerber Laura C. H.,

Peters Jonas C.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001199

Subject(s) - osmium , ruthenium , reactivity (psychology) , moiety , chemistry , electron paramagnetic resonance , character (mathematics) , redox , photochemistry , stereochemistry , organic chemistry , physics , catalysis , mathematics , nuclear magnetic resonance , medicine , alternative medicine , geometry , pathology

Radically complex : Well‐defined mononuclear Ru I and Os I complexes (see scheme) have metalloradical character, as indicated by EPR spectroscopy and DFT calculations. The Ru I and Os I metalloradicals exhibit both one‐electron and two‐electron redox reactivity. The latter process affords unusual imido complexes with substantial radical character on the {ArN} moiety.

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