Unprecedented Rate Enhancements of Hydrogen‐Atom Transfer to a Manganese(V)–Oxo Corrolazine Complex | Zendy

Prokop Katharine A. | Zendy; de Visser Sam P. | Zendy; Goldberg David P. | Zendy

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Unprecedented Rate Enhancements of Hydrogen‐Atom Transfer to a Manganese(V)–Oxo Corrolazine Complex

Author(s) -

Prokop Katharine A.,

de Visser Sam P.,

Goldberg David P.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201001172

Subject(s) - manganese , hydrogen atom , hydrogen , atom (system on chip) , chemistry , materials science , metallurgy , computer science , organic chemistry , embedded system , group (periodic table)

Runaway reactivity : A manganese(V)–oxo porphyrinoid complex displays an unprecedented increase in reaction rate for a hydrogen‐atom abstraction upon addition of anionic axial ligands (X=F − and CN − ; see scheme). Density functional theory calculations are in excellent agreement with experiment, and provide insight into the origins of these remarkable axial ligand effects.

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