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Unprecedented Rate Enhancements of Hydrogen‐Atom Transfer to a Manganese(V)–Oxo Corrolazine Complex
Author(s) -
Prokop Katharine A.,
de Visser Sam P.,
Goldberg David P.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001172
Subject(s) - manganese , hydrogen atom , hydrogen , atom (system on chip) , chemistry , materials science , metallurgy , computer science , organic chemistry , embedded system , group (periodic table)
Runaway reactivity : A manganese(V)–oxo porphyrinoid complex displays an unprecedented increase in reaction rate for a hydrogen‐atom abstraction upon addition of anionic axial ligands (X=F − and CN − ; see scheme). Density functional theory calculations are in excellent agreement with experiment, and provide insight into the origins of these remarkable axial ligand effects.