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Cyclohexyne Cycloinsertion by an Annulative Ring Expansion Cascade
Author(s) -
Gampe Christian M.,
Boulos Samy,
Carreira Erick M.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001137
Subject(s) - ring (chemistry) , cascade , computer science , information retrieval , world wide web , combinatorial chemistry , chemistry , organic chemistry , chromatography
Cyclohexyne steps into the ring! Cyclohexyne is used for the facile synthesis of polycyclic, medium sized rings. Its insertion into cyclic ketones enables rapid access to densely functionalized building blocks.