Premium
Synthesis of Dibenzothiophenes and Related Classes of Heterocycles by Using Functionalized Dithiocarbamates
Author(s) -
Kienle Marcel,
Unsinn Andreas,
Knochel Paul
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201001025
Subject(s) - benzothiophene , chemistry , ring (chemistry) , electrophile , benzofuran , catalysis , palladium , transition metal , aryl , sulfur , combinatorial chemistry , organic chemistry , thiophene , alkyl
A round trip : Readily available dithiocarbamates can undergo ring closure to give functionalized sulfur heterocycles (see scheme). These heteroaromatic compounds can be further functionalized by directed alumination and subsequently trapped with various electrophiles.