Highly Active Chiral Ruthenium‐Based Metathesis Catalysts through a Monosubstitution in the N‐Heterocyclic Carbene | Zendy

Tiede Sascha | Zendy; Berger Anke | Zendy; Schlesiger David | Zendy; Rost Daniel | Zendy; Lühl Anja | Zendy; Blechert Siegfried | Zendy

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Highly Active Chiral Ruthenium‐Based Metathesis Catalysts through a Monosubstitution in the N‐Heterocyclic Carbene

Author(s) -

Tiede Sascha,

Berger Anke,

Schlesiger David,

Rost Daniel,

Lühl Anja,

Blechert Siegfried

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000940

Subject(s) - carbene , ruthenium , metathesis , catalysis , selectivity , combinatorial chemistry , chemistry , ligand (biochemistry) , carbon atom , ring (chemistry) , organic chemistry , polymerization , polymer , biochemistry , receptor

Single (substitution) is better : New chiral ruthenium metathesis (pre)catalysts with a monosubstituted carbon atom in the N‐heterocyclic carbene ligand are highly stable in solution, initiate easily, show very high enantioselectivity and excellent E selectivity in asymmetric ring‐opening cross‐metathesis (see scheme).

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