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Porphyrin “Lego Block” Strategy To Construct Directly meso–β Doubly Linked Porphyrin Rings
Author(s) -
Song Jianxin,
Aratani Naoki,
Kim Pyosang,
Kim Dongho,
Shinokubo Hiroshi,
Osuka Atsuhiro
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000915
Subject(s) - porphyrin , block (permutation group theory) , construct (python library) , chemistry , coupling (piping) , photochemistry , materials science , computer science , mathematics , combinatorics , composite material , programming language
Clicking together : The Suzuki–Miyaura coupling of β,β′‐diborylated porphyrin blocks and meso,meso′‐dibrominated porphyrin blocks was used for the construction of directly meso–β doubly linked porphyrin rings including two tetraporphyrin rings, hexaporphyrin rings, and a bridged heptaporphyrin (see picture).