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Synthesis, Structure, and Reactivity of a Stabilized Phosphiranylium Salt
Author(s) -
Jansen Helen,
Läng Florian B.,
Slootweg J. Chris,
Ehlers Andreas W.,
Lutz Martin,
Lammertsma Koop,
Grützmacher Hansjörg
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000901
Subject(s) - trifluoromethanesulfonate , carbene , chemistry , salt (chemistry) , reactivity (psychology) , nucleophile , ion , combinatorial chemistry , stereochemistry , polymer chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology
Charged! Combining Me BABAR‐Phos and methyl triflate affords an amino‐stabilized phosphiranylium ion (see picture; C gray, N blue, P orange), which undergoes various nucleophilic addition reactions to give P‐substituted phosphiranes and an N‐heterocyclic carbene stabilized phosphiranylium cation.