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A Metal–Organic Framework as an Electrocatalyst for Ethanol Oxidation
Author(s) -
Yang Lifen,
Kinoshita Shozo,
Yamada Teppei,
Kanda Seiichi,
Kitagawa Hiroshi,
Tokunaga Makoto,
Ishimoto Takayoshi,
Ogura Teppei,
Nagumo Ryo,
Miyamoto Akira,
Koyama Michihisa
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000863
Subject(s) - electrocatalyst , catalysis , ethanol , copper , metal , metal organic framework , inorganic chemistry , chemistry , noble metal , precious metal , methanol , nuclear chemistry , materials science , electrochemistry , organic chemistry , electrode , adsorption
No need for nobles : The copper‐based metal–organic framework material N , N ′‐bis(2‐hydroxyethyl)dithiooxamidatocopper(II) (see picture, Cu pink, N blue, S yellow, O red, C gray, H white) is an active catalyst for ethanol electrooxidation. The performance of this noble‐metal‐free material is comparable to those of some reported Pt‐based catalysts.