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Water as an Oxygen Source: Synthesis, Characterization, and Reactivity Studies of a Mononuclear Nonheme Manganese(IV) Oxo Complex
Author(s) -
Sawant Sarvesh C.,
Wu Xiujuan,
Cho Jaeheung,
Cho KyungBin,
Kim Sun Hee,
Seo Mi Sook,
Lee YongMin,
Kubo Minoru,
Ogura Takashi,
Shaik Sason,
Nam Wonwoo
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000819
Subject(s) - manganese , reactivity (psychology) , cerium , chemistry , oxygen , primary (astronomy) , alkyl , molecule , characterization (materials science) , alcohol , organic chemistry , combinatorial chemistry , nanotechnology , materials science , medicine , physics , alternative medicine , pathology , astronomy
The source of the problem : Experiments with isotopically labeled water can be used to unambiguously assign the source of oxygen in a nonheme manganese(IV) oxo complex. The complex, which was generated using water as an oxygen source and cerium(IV) as an oxidant (see picture), shows reactivities in the activation of CH bonds of alkyl‐functionalized aromatic molecules and the oxidation of aromatic substrates (sub) and benzyl alcohol.