Reversible Thermally and Photoinduced Electron Transfer in a Cyano‐Bridged {Fe 2 Co 2 } Square Complex | Zendy

Zhang Yuanzhu | Zendy; Li Dongfeng | Zendy; Clérac Rodolphe | Zendy; Kalisz Marguerite | Zendy; Mathonière Corine | Zendy; Holmes Stephen M. | Zendy

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Reversible Thermally and Photoinduced Electron Transfer in a Cyano‐Bridged {Fe 2 Co 2 } Square Complex

Author(s) -

Zhang Yuanzhu,

Li Dongfeng,

Clérac Rodolphe,

Kalisz Marguerite,

Mathonière Corine,

Holmes Stephen M.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000765

Subject(s) - prussian blue , intramolecular force , square (algebra) , electron transfer , bistability , optical bistability , electron , materials science , crystallography , square pyramidal molecular geometry , photochemistry , chemical physics , chemistry , condensed matter physics , nuclear magnetic resonance , nonlinear optics , optics , crystal structure , electrochemistry , optoelectronics , physics , stereochemistry , electrode , laser , geometry , quantum mechanics , mathematics

Flip to be square : Structural, spectroscopic, magnetic, and photomagnetic studies conclusively demonstrate that a tetranuclear cyanometalate {Fe 2 Co 2 } complex undergoes reversible thermally and light‐induced changes in its optical and magnetic properties. This bistability is induced by an intramolecular electron transfer, as observed in three‐dimensional Co/Fe Prussian blue compounds (see picture).

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