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Palladium(II)‐Catalyzed Oxidative Carbocyclization of Aza‐Enallenes
Author(s) -
Persson Andreas K. Å.,
Bäckvall JanE.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000726
Subject(s) - palladium , catalysis , benzoquinone , oxidative phosphorylation , chemistry , diene , sequence (biology) , combinatorial chemistry , organic chemistry , biochemistry , natural rubber
Live and let diene : A palladium(II)‐catalyzed oxidative carbocyclization reaction of aza‐enallenes provides access to potentially valuable heterocyclic dienes. In the presence of a dieneophile during the carbocyclization step, the products can react further in a one‐pot cyclization/Diels–Alder sequence to give polycyclic products. BQ= para ‐benzoquinone.