Premium
Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization
Author(s) -
Selander Nicklas,
Willy Benjamin,
Szabó Kálmán J.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000690
Subject(s) - borylation , hypervalent molecule , transmetalation , chemistry , palladium , pincer movement , catalysis , alkene , surface modification , photochemistry , medicinal chemistry , combinatorial chemistry , iodine , organic chemistry , aryl , alkyl
The CH borylation of simple alkenes catalyzed by palladium pincer complex 1 was performed in the presence of hypervalent iodine and bis(pinacolato)diboron compounds. The borylation reaction probably occurs by a Pd II →Pd IV oxidation–diboronate transmetalation sequence. TFA=trifluoroacetate.