Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization | Zendy

Selander Nicklas | Zendy; Willy Benjamin | Zendy; Szabó Kálmán J. | Zendy

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Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization

Author(s) -

Selander Nicklas,

Willy Benjamin,

Szabó Kálmán J.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000690

Subject(s) - borylation , hypervalent molecule , transmetalation , chemistry , palladium , pincer movement , catalysis , alkene , surface modification , photochemistry , medicinal chemistry , combinatorial chemistry , iodine , organic chemistry , aryl , alkyl

The CH borylation of simple alkenes catalyzed by palladium pincer complex 1 was performed in the presence of hypervalent iodine and bis(pinacolato)diboron compounds. The borylation reaction probably occurs by a Pd II →Pd IV oxidation–diboronate transmetalation sequence. TFA=trifluoroacetate.

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