A Nanoscopic 3D Polyferrocenyl Assembly: The Triacontakaihexa(ferrocenylmethylthiolate) [Ag 48 (μ 4 ‐S) 6 (μ 2/3 ‐SCH 2 Fc) 36 ] | Zendy

Ahmar Siawash | Zendy; MacDonald Daniel G. | Zendy; Vijayaratnam Niranjan | Zendy; Battista Taylor L. | Zendy; Workentin Mark S. | Zendy; Corrigan John F. | Zendy

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A Nanoscopic 3D Polyferrocenyl Assembly: The Triacontakaihexa(ferrocenylmethylthiolate) [Ag 48 (μ 4 ‐S) 6 (μ 2/3 ‐SCH 2 Fc) 36 ]

Author(s) -

Ahmar Siawash,

MacDonald Daniel G.,

Vijayaratnam Niranjan,

Battista Taylor L.,

Workentin Mark S.,

Corrigan John F.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000686

Subject(s) - nanoscopic scale , crystallography , cyclic voltammetry , diffraction , materials science , orange (colour) , yield (engineering) , x ray crystallography , analytical chemistry (journal) , nanotechnology , chemistry , optics , electrochemistry , physics , metallurgy , organic chemistry , electrode

The molecular nanocluster [Ag 48 (μ 4 ‐S) 6 (μ 2/3 ‐SCH 2 Fc) 36 ] ( 1 ) (see picture; Ag blue, S yellow, Fe orange, C gray; Fc=ferrocenyl) has been prepared in good yield and characterized by single‐crystal X‐ray diffraction. The 36 ferrocenylmethylthiolate ligands envelop the AgS core. Cyclic voltammetry of 1 displays one reversible oxidation wave.

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