Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboroxines to β,β‐Disubstituted α,β‐Unsaturated Ketones | Zendy

Shintani Ryo | Zendy; Takeda Momotaro | Zendy; Nishimura Takahiro | Zendy; Hayashi Tamio | Zendy

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Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Arylboroxines to β,β‐Disubstituted α,β‐Unsaturated Ketones

Author(s) -

Shintani Ryo,

Takeda Momotaro,

Nishimura Takahiro,

Hayashi Tamio

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000467

Subject(s) - stereocenter , rhodium , enantiomer , chemistry , catalysis , ligand (biochemistry) , combinatorial chemistry , organic chemistry , enantioselective synthesis , stereochemistry , biochemistry , receptor

Lock, Stock and Two Smoking Barrelenes : The rhodium‐catalyzed 1,4‐addition of readily available arylboronic acid anhydrides to simple β,β‐disubstituted α,β‐unsaturated ketones creates quaternary carbon stereocenters with high enantiomeric excesses using a chiral tetrafluorobenzobarrelene ligand.

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