Cover Picture: Ag II SO 4 : A Genuine Sulfate of Divalent Silver with Anomalously Strong One‐Dimensional Antiferromagnetic Interactions (Angew. Chem. Int. Ed. 9/2010) | Zendy

Malinowski Przemysław J. | Zendy; Derzsi Mariana | Zendy; Mazej Zoran | Zendy; Jagličić Zvonko | Zendy; Gaweł Bartłomiej | Zendy; Łasocha Wiesław | Zendy; Grochala Wojciech | Zendy

Premium

Cover Picture: Ag II SO 4 : A Genuine Sulfate of Divalent Silver with Anomalously Strong One‐Dimensional Antiferromagnetic Interactions (Angew. Chem. Int. Ed. 9/2010)

Author(s) -

Malinowski Przemysław J.,

Derzsi Mariana,

Mazej Zoran,

Jagličić Zvonko,

Gaweł Bartłomiej,

Łasocha Wiesław,

Grochala Wojciech

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000368

Subject(s) - antiferromagnetism , cover (algebra) , crystallography , sulfate , transition metal , divalent metal , divalent , chemistry , coupling (piping) , semiconductor , metal , condensed matter physics , inorganic chemistry , materials science , physics , metallurgy , catalysis , optoelectronics , organic chemistry , mechanical engineering , engineering

Deep‐black AgSO4 (Mr. Hyde) is a narrow‐bandgap semiconductor and an extremely strong oxidant. W. Grochala and co‐workers show in their Communication on page 1683 ff . that it differs in all important physicochemical properties from its lighter congener, unreactive colorless CuSO 4 (Dr. Jekyll). Unusually strong antiferromagnetic coupling persists up to the temperature at which AgSO 4 thermally decomposes (ca. 120 °C), which sets it apart from all other transition‐metal sulfates.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research