A Rational Approach to the Ionothermal Synthesis of an AlPO 4  Molecular Sieve with an LTA‐Type Framework | Zendy

Fayad Elie J. | Zendy; Bats Nicolas | Zendy; Kirschhock Christine E. A. | Zendy; Rebours Bernadette | Zendy; Quoineaud AnneAgathe | Zendy; Martens Johan A. | Zendy

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A Rational Approach to the Ionothermal Synthesis of an AlPO 4 Molecular Sieve with an LTA‐Type Framework

Author(s) -

Fayad Elie J.,

Bats Nicolas,

Kirschhock Christine E. A.,

Rebours Bernadette,

Quoineaud AnneAgathe,

Martens Johan A.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000304

Subject(s) - molecular sieve , sodalite , tetramethylammonium , ionic liquid , zeolite , ion , chemistry , fluoride , structuring , chemical engineering , combinatorial chemistry , computer science , crystallography , organic chemistry , inorganic chemistry , engineering , catalysis , finance , adsorption , economics

Structurally sound : The synthesis of AlPO 4 ‐LTA zeolite in ionic liquids employs 1‐benzyl‐3‐methylimidazolium, tetramethylammonium, and fluoride ions for structuring α cages, sodalite cages, and cubes (see picture; C gray, N blue, O red, Al and P purple, F green). Selective removal of 1‐benzyl‐3‐methylimidazolium ions results in a stable AlPO 4 ‐LTA molecular sieve. The α cages of AlPO 4 ‐LTA framework can be evacuated while maintaining structural integrity.

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