Premium
Structurally Stimulated Deprotonation/Alumination of the TMP Anion
Author(s) -
Conway Ben,
Kennedy Alan R.,
Mulvey Robert E.,
Robertson Stuart D.,
Álvarez Joaquin García
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201000181
Subject(s) - deprotonation , ion , chemistry , business , organic chemistry
Coerced conversion : Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ‐TMP*)(μ‐ i Bu)Al( i Bu)] was obtained where TMP* represents a CH 3 ‐ and NH‐deprotonated dianionic variant of TMP (see scheme).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom