A Simple Route to Univalent Gallium Salts of Weakly Coordinating Anions | Zendy

Slattery John M. | Zendy; Higelin Alexander | Zendy; Bayer Thomas | Zendy; Krossing Ingo | Zendy

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A Simple Route to Univalent Gallium Salts of Weakly Coordinating Anions

Author(s) -

Slattery John M.,

Higelin Alexander,

Bayer Thomas,

Krossing Ingo

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000156

Subject(s) - gallium , homoleptic , phosphine , simple (philosophy) , computer science , ion , chemistry , combinatorial chemistry , organic chemistry , catalysis , philosophy , metal , epistemology

Pyramidal [Ga(PPh 3 ) 3 ] + (see picture) is the first structurally characterized homoleptic gallium–phosphine complex. The synthesis of this ion was aided by the development of a facile route to gallium(I) salts with weakly coordinating anions (WCAs). These salts are an outstanding source of gallium in the oxidation state +1 for the generation of previously unknown low‐valent gallium compounds.

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