Formation of a 1‐Zircona‐2,5‐disilacyclopent‐3‐yne: Coordination of 1,4‐Disilabutatriene to Zirconocene? | Zendy

Lamač Martin | Zendy; Spannenberg Anke | Zendy; Jiao Haijun | Zendy; Hansen Sven | Zendy; Baumann Wolfgang | Zendy; Arndt Perdita | Zendy; Rosenthal Uwe | Zendy

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Formation of a 1‐Zircona‐2,5‐disilacyclopent‐3‐yne: Coordination of 1,4‐Disilabutatriene to Zirconocene?

Author(s) -

Lamač Martin,

Spannenberg Anke,

Jiao Haijun,

Hansen Sven,

Baumann Wolfgang,

Arndt Perdita,

Rosenthal Uwe

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201000021

Subject(s) - metallacycle , alkyne , crystallography , atom (system on chip) , chemistry , triple bond , metal , stereochemistry , materials science , x ray crystallography , polymer chemistry , double bond , physics , organic chemistry , catalysis , computer science , diffraction , optics , embedded system

Alkyne under stress : A novel metallacycle containing one Zr atom, two Si atoms, and a CC bond has been prepared and its structure elucidated (Zr green, Si blue, C gray). According to X‐ray data, spectral properties, and DFT calculations, the bonding situation in this compound is characterized as a 1‐metalla‐2,5‐disilacyclopent‐3‐yne with a weak metal–triple‐bond interaction.

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