Nickel‐Catalyzed Amination of Aryl Pivalates by the Cleavage of Aryl CO Bonds | Zendy

Shimasaki Toshiaki | Zendy; Tobisu Mamoru | Zendy; Chatani Naoto | Zendy

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Nickel‐Catalyzed Amination of Aryl Pivalates by the Cleavage of Aryl CO Bonds

Author(s) -

Shimasaki Toshiaki,

Tobisu Mamoru,

Chatani Naoto

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200907287

Subject(s) - amination , aryl , chemistry , catalysis , carbene , electrophilic amination , cleavage (geology) , bond cleavage , nickel , electrophile , organic chemistry , medicinal chemistry , combinatorial chemistry , materials science , alkyl , fracture (geology) , composite material

Catalytic amination : The title reaction demonstrates the use of aryl carboxylates as suitable electrophilic coupling substrates in catalytic amination reactions. N‐heterocyclic carbene ligands and NaO t Bu promote the amination of aryl pivalates through the cleavage of normally unreactive aryl carbon–oxygen bonds (see scheme; cod=cyclooctadiene).

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