Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II) | Zendy

Cao Peng | Zendy; Deng Chao | Zendy; Zhou YouYun | Zendy; Sun XiuLi | Zendy; Zheng JunCheng | Zendy; Xie Zuowei | Zendy; Tang Yong | Zendy

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Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II)

Author(s) -

Cao Peng,

Deng Chao,

Zhou YouYun,

Sun XiuLi,

Zheng JunCheng,

Xie Zuowei,

Tang Yong

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200907266

Subject(s) - oxazoline , catalysis , copper , trifluoromethyl , chemistry , tris , enantioselective synthesis , boron , medicinal chemistry , combinatorial chemistry , polymer chemistry , organic chemistry , biochemistry , alkyl

Beverly Hills copper(II) : A highly efficient catalytic asymmetric Nazarov reaction has been developed through control of the enantioselectivity of the cyclization step, affording chiral O‐heterohexahydroindenones in excellent yields with excellent enantioselectivity and diastereoselectivity. HFIP=hexafluoro‐2‐propanol, B ArF = tetrakis[3,5‐bis(trifluoromethyl)phenyl] borate.

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