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A Versatile and Highly Reactive Polyfluorinated Hypervalent Iodine(III) Compound
Author(s) -
Schäfer Sascha,
Wirth Thomas
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200907134
Subject(s) - hypervalent molecule , iodine , reagent , chemistry , combinatorial chemistry , stoichiometry , iodine compounds , reactive intermediate , organic chemistry , catalysis
Hyper‐reactive : A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one‐pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well‐established reactions (e.g. C–C bond cleavage and the conversion of alcohols into aldehydes).