Synthesis of Ideal AM‐6 and Elucidation of V 4+ ‐to‐O Charge Transfer in Vanadate Quantum Wires | Zendy

Datta Shuvo Jit | Zendy; Yoon Kyung Byung | Zendy

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Synthesis of Ideal AM‐6 and Elucidation of V 4+ ‐to‐O Charge Transfer in Vanadate Quantum Wires

Author(s) -

Datta Shuvo Jit,

Yoon Kyung Byung

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200907088

Subject(s) - vanadate , charge (physics) , band gap , zeolite , ligand (biochemistry) , metal , chemistry , ideal (ethics) , materials science , inorganic chemistry , crystallography , physics , catalysis , optoelectronics , organic chemistry , quantum mechanics , biochemistry , receptor , epistemology , philosophy

Vanadosilicate zeolite AM‐6, which contains a 3D array of vanadate (V IV O 3 2− ) quantum wires (see picture), was prepared as high‐quality crystals (free from V V , titanosilicate seeds, and pore‐blocking organic template cations) from inexpensive V 2 O 5 . The linear dependence of λ max and band‐gap energy E g on the partial charge on the framework O atoms reveal that the UV band of AM‐6 is due to V IV ‐to‐O metal‐to‐ligand charge transfer.

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