Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents | Zendy

Hachiya Hitoshi | Zendy; Hirano Koji | Zendy; Satoh Tetsuya | Zendy; Miura Masahiro | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Nickel‐Catalyzed Direct CH Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents

Author(s) -

Hachiya Hitoshi,

Hirano Koji,

Satoh Tetsuya,

Miura Masahiro

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906996

Subject(s) - organosilicon , catalysis , aryl , reagent , nickel , chemistry , surface modification , combinatorial chemistry , polymer chemistry , organic chemistry , alkyl

Breaking the Si‐lence : The direct cross‐coupling of heteroarenes with aryl‐ or alkenylsilanes proceeds efficiently, in the presence of a nickel catalyst, to create a wide range of aryl–and alkenyl–heteroaryl bonds efficiently (see scheme; DMAc= N , N ‐dimethylacetamide, bpy=2,2′‐bipyridine). This catalysis represents a new avenue for using organosilanes in the catalytic CH functionalization chemistry.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research