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Protonation‐Induced Rearrangement of an Oxaphosphirane Complex
Author(s) -
Marinas Pérez Janaina,
Helten Holger,
Donnadieu Bruno,
Reed Christopher A.,
Streubel Rainer
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906825
Subject(s) - protonation , phosphonium , tungsten , chemistry , ring (chemistry) , ligand (biochemistry) , methylene , methylene blue , photochemistry , medicinal chemistry , polymer chemistry , ion , organic chemistry , receptor , catalysis , biochemistry , photocatalysis
O‐Protonation of an oxaphosphirane tungsten complex causes ring opening and the formation of a POH functional methylene phosphonium ligand bound side‐on to the tungsten center (see scheme).