Non‐Innocent Behavior of a Tridentate NHC Chelating Ligand Coordinated onto a Zirconium(IV) Center | Zendy

Romain Charles | Zendy; Miqueu Karinne | Zendy; Sotiropoulos JeanMarc | Zendy; BelleminLaponnaz Stéphane | Zendy; Dagorne Samuel | Zendy

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Non‐Innocent Behavior of a Tridentate NHC Chelating Ligand Coordinated onto a Zirconium(IV) Center

Author(s) -

Romain Charles,

Miqueu Karinne,

Sotiropoulos JeanMarc,

BelleminLaponnaz Stéphane,

Dagorne Samuel

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906702

Subject(s) - zirconium , chelation , carbene , ligand (biochemistry) , center (category theory) , chemistry , metal , combinatorial chemistry , stereochemistry , medicinal chemistry , polymer chemistry , crystallography , organic chemistry , catalysis , biochemistry , receptor

NHC me, now you don′t : A tridentate bis(aryloxide)NHC‐chelating ligand readily coordinates to Zr IV and undergoes an unprecedented THF‐promoted benzyl migration from the zirconium metal center to the C carbene atom of the NHC. NHC=N‐heterocyclic carbene.

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