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A SulfurSulfur Cross‐Linked Polymer Synthesized from a Polymerizable Dithiocarbamate as a Source of Dormant Radicals
Author(s) -
GarcíaCon Luis Miguel,
Whitcombe Michael J.,
Piletska Elena V.,
Piletsky Sergey A.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906676
Subject(s) - dithiocarbamate , sulfur , polymer , radical , chemistry , nitrogen , polymer chemistry , organic chemistry
Cross on UV light : A polymer bearing dithiocarbamate ester groups, linked to the polymer backbone through the dithiocarbamate nitrogen atom is capable of reversible cross‐linking and de‐linking through photochemical rearrangement of the pendant groups (see scheme).