Total Synthesis of Auripyrones A and B and Determination of the Absolute Configuration of Auripyrone B | Zendy

Hayakawa Ichiro | Zendy; Takemura Takuma | Zendy; Fukasawa Emi | Zendy; Ebihara Yuta | Zendy; Sato Natsuki | Zendy; Nakamura Takayasu | Zendy; Suenaga Kiyotake | Zendy; Kigoshi Hideo | Zendy

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Total Synthesis of Auripyrones A and B and Determination of the Absolute Configuration of Auripyrone B

Author(s) -

Hayakawa Ichiro,

Takemura Takuma,

Fukasawa Emi,

Ebihara Yuta,

Sato Natsuki,

Nakamura Takayasu,

Suenaga Kiyotake,

Kigoshi Hideo

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906662

Subject(s) - absolute configuration , aldol reaction , absolute (philosophy) , content (measure theory) , key (lock) , computer science , total synthesis , stereochemistry , chemistry , mathematics , philosophy , organic chemistry , epistemology , catalysis , mathematical analysis , computer security

The winner takes it al‐dol : The total synthesis of auripyrones A and B was achieved using a diastereoselective aldol‐type reaction with 2,6‐diethyl‐3,5‐dimethyl‐4‐pyrone as a key step. The stereostructure and absolute configuration of auripyrone B has also been determined.

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