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Aufbaureaktion Redux: Scalable Production of Precision Hydrocarbons from AlR 3 (R=Et or i Bu) by Dialkyl Zinc Mediated Ternary Living Coordinative Chain‐Transfer Polymerization
Author(s) -
Wei Jia,
Zhang Wei,
Sita Lawrence R.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906658
Subject(s) - scalability , redux , production (economics) , ternary operation , zinc , computer science , polymerization , chemistry , combinatorial chemistry , materials science , organic chemistry , database , programming language , polymer , economics , composite material , macroeconomics
Metal ménage à trois : Rapid and reversible chain transfer under living conditions between an active transition‐metal propagating species, AlR 3 as a primary surrogate, and a catalytic amount of ZnR 2 as a secondary surrogate and chain‐transfer mediator provides a cost‐effective, scalable process for the production of precision hydrocarbons.