Self‐Repair of a One‐Dimensional Molecular Assembly in Mesoporous Silica by a Nanoscopic Template Effect | Zendy

Lintang Hendrik O. | Zendy; Kinbara Kazushi | Zendy; Tanaka Kenichi | Zendy; Yamashita Takashi | Zendy; Aida Takuzo | Zendy

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Self‐Repair of a One‐Dimensional Molecular Assembly in Mesoporous Silica by a Nanoscopic Template Effect

Author(s) -

Lintang Hendrik O.,

Kinbara Kazushi,

Tanaka Kenichi,

Yamashita Takashi,

Aida Takuzo

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906578

Subject(s) - nanoscopic scale , lamellar structure , materials science , mesoporous silica , silicate , luminescence , hexagonal crystal system , nanotechnology , self assembly , chemical engineering , mesoporous material , crystallography , chemistry , composite material , optoelectronics , organic chemistry , catalysis , engineering

Upon confinement of a trinuclear gold(I) pyrazolate complex in a hexagonal silicate channel, the luminescence center formed by a Au I –Au I metallophilic interaction is not only protected against thermal disruption but also strongly encouraged to self‐recover from a heat‐induced structural damage. This nanoscopic template effect is negligible for a lamellar silica framework.

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