One‐Pot Synthesis of Benzimidazoles by Simultaneous Photocatalytic and Catalytic Reactions on Pt@TiO 2  Nanoparticles | Zendy

Shiraishi Yasuhiro | Zendy; Sugano Yoshitsune | Zendy; Tanaka Shunsuke | Zendy; Hirai Takayuki | Zendy

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One‐Pot Synthesis of Benzimidazoles by Simultaneous Photocatalytic and Catalytic Reactions on Pt@TiO 2 Nanoparticles

Author(s) -

Shiraishi Yasuhiro,

Sugano Yoshitsune,

Tanaka Shunsuke,

Hirai Takayuki

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906573

Subject(s) - dehydrogenation , photocatalysis , platinum , catalysis , platinum nanoparticles , nanoparticle , chemistry , combinatorial chemistry , photochemistry , organic chemistry , nanotechnology , materials science

Dual platinum action : A one‐pot catalytic synthesis of benzimidazoles from the photoirradiation of an alcohol solution containing an ortho ‐arylenediamine and Pt@TiO 2 nanoparticles is described. This reaction proceeded by the platinum‐assisted photocatalytic oxidation of an alcohol and a catalytic dehydrogenation of the intermediates on the surface of platinum nanoparticles.

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