The Syntheses and Structure of the Vanadium(IV) and Vanadium(V) Binary Azides V(N 3 ) 4 , [V(N 3 ) 6 ] 2− , and [V(N 3 ) 6 ] − | Zendy

Haiges Ralf | Zendy; Boatz Jerry A. | Zendy; Christe Karl O. | Zendy

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The Syntheses and Structure of the Vanadium(IV) and Vanadium(V) Binary Azides V(N 3 ) 4 , [V(N 3 ) 6 ] 2− , and [V(N 3 ) 6 ] −

Author(s) -

Haiges Ralf,

Boatz Jerry A.,

Christe Karl O.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200906537

Subject(s) - vanadium , azide , chemistry , binary number , ion , ion exchange , crystallography , inorganic chemistry , medicinal chemistry , organic chemistry , mathematics , arithmetic

Shock‐sensitive and highly explosive V(N 3 ) 4 was prepared from VF 4 and Me 3 SiN 3 by fluoride–azide exchange. Salts of the [V(N 3 ) 6 ] 2− anion (see picture) were obtained by treatment of the neutral tetraazide with ionic azides. Vanadium(V) azide, the only binary vanadium(V) compound known apart from VF 5 , VF 6 − , and V 2 O 5 , was successfully prepared from the VF 6 − anion.

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