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Transmetalation Supported by a Pt II Cu I Bond
Author(s) -
Moret MarcEtienne,
Serra Daniel,
Bach Andreas,
Chen Peter
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906480
Subject(s) - transmetalation , chemistry , thermochemistry , dissociation (chemistry) , platinum , copper , crystal structure , ion , bond dissociation energy , inorganic chemistry , crystallography , catalysis , organic chemistry
Passing Me over : Platinum‐to‐copper methyl transfer is observed upon collision‐induced dissociation (CID) of the cations formed by the interaction of the [(R 3 P)Cu] + fragment with [(dmpe)PtMe 2 ] (R=Me, Ph, Cy, t Bu; dmpe=bis(dimethylphosphino)ethane; see X‐ray crystal structure of coordination spheres for R= t Bu). The thermochemistry of these processes for R=Me is investigated by mass‐spectrometric methods.