Premium
Transmetalation Supported by a Pt II Cu I Bond
Author(s) -
Moret MarcEtienne,
Serra Daniel,
Bach Andreas,
Chen Peter
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906480
Subject(s) - transmetalation , chemistry , thermochemistry , dissociation (chemistry) , platinum , copper , crystal structure , ion , bond dissociation energy , inorganic chemistry , crystallography , catalysis , organic chemistry
Passing Me over : Platinum‐to‐copper methyl transfer is observed upon collision‐induced dissociation (CID) of the cations formed by the interaction of the [(R 3 P)Cu] + fragment with [(dmpe)PtMe 2 ] (R=Me, Ph, Cy, t Bu; dmpe=bis(dimethylphosphino)ethane; see X‐ray crystal structure of coordination spheres for R= t Bu). The thermochemistry of these processes for R=Me is investigated by mass‐spectrometric methods.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom