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Ionothermal Synthesis of Extra‐Large‐Pore Open‐Framework Nickel Phosphite 5 H 3 O⋅[Ni 8 (HPO 3 ) 9 Cl 3 ]⋅1.5 H 2 O: Magnetic Anisotropy of the Antiferromagnetism
Author(s) -
Xing Hongzhu,
Yang Weiting,
Su Tan,
Li Yi,
Xu Jin,
Nakano Takehito,
Yu Jihong,
Xu Ruren
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906471
Subject(s) - microporous material , nickel , ring (chemistry) , chloride , anisotropy , crystallography , magnetocrystalline anisotropy , layer (electronics) , materials science , magnetic anisotropy , chemistry , nanotechnology , physics , metallurgy , organic chemistry , optics , magnetic field , magnetization , quantum mechanics
Microporous magnets : The structure (inset) of the title compound features two‐dimensional nickel–oxygen/chloride 18‐ring layers, which are stacked along the c axis and pillared by HPO 3 units. Magnetic anisotropy measurements (see picture) on aligned single crystals indicate that the magnetic easy axis is perpendicular to the layer plane.