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Directed Orthogonal Self‐Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation
Author(s) -
Yu Liting,
Wang Zheng,
Wu Jiang,
Tu Shujiang,
Ding Kuiling
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906405
Subject(s) - enantioselective synthesis , asymmetric hydrogenation , olefin fiber , ligand (biochemistry) , catalysis , chiral ligand , combinatorial chemistry , chemistry , materials science , organic chemistry , biochemistry , receptor
Three in one : Orthogonal coordination of Fe II and Rh I with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various functionalized olefin derivatives.