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Palladium‐Catalyzed Carbonylation/Acyl Migratory Insertion Sequence
Author(s) -
Zhang Zhenhua,
Liu Yiyang,
Gong Mingxing,
Zhao Xiaokun,
Zhang Yan,
Wang Jianbo
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906349
Subject(s) - palladium , carbonylation , diazo , carbon monoxide , sequence (biology) , catalysis , aryl , chemistry , asynchronous communication , organic chemistry , combinatorial chemistry , computer science , telecommunications , biochemistry , alkyl
On the move : A palladium‐catalyzed reaction of aryl iodides, diazo compounds or N ‐tosylhydrazones, and carbon monoxide affords β‐oxo esters or ketones/enones (see scheme; DCE=1,2‐dichloroethane). The products are delivered with high efficiency through the title sequence.