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Spin Divergence Induced by Exohedral Modification: ESR Study of Sc 3 C 2 @C 80 Fulleropyrrolidine
Author(s) -
Wang Taishan,
Wu Jingyi,
Xu Wei,
Xiang Junfeng,
Lu Xin,
Li Bao,
Jiang Li,
Shu Chunying,
Wang Chunru
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200906325
Subject(s) - paramagnetism , fullerene , endohedral fullerene , materials science , electron paramagnetic resonance , spin (aerodynamics) , metallofullerene , nanotechnology , carbide , nitride , chemical physics , chemistry , physics , nuclear magnetic resonance , condensed matter physics , organic chemistry , thermodynamics , layer (electronics) , composite material
The paramagnetic properties of the endohedral fullerene Sc 3 C 2 @C 80 are adjustable by exohedral modification by the Prato reaction (see picture). Analysis of spin densities and endocluster dynamics reveal unique paramagnetic properties of the Sc 3 C 2 @C 80 fulleropyrrolidine and provide general insight into the addend‐dependent paramagnetic behavior of endohedral fullerenes.